Those individuals who often do wicked deeds and must be stopped by the heroes.
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- Machine Men
- Madame Masque
- Magneto
- Man-Spider
- Man-Spider (Marvel Universe)
- Man-Spider (Spider-Man (Six Arms) Universe)
- Man-Wolf
- Mandarin
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- Master Mold
- Maximus
- Medusa
- Michael Morbius
- Miles Warren
- Miles Warren (Spider-Carnage Universe)
- Miranda Wilson
- Miriam
- Miss Allure
- Mister Sinister
- MODOK
- Mojo
- Mole Man
- Moonstone
- Morph
- Ms. Marvel
- Mysterio
- Mystique
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